By the diagram above, the farthest two connections are for audio, the closest is for video and the one in between is ground. The position of the video being closest to the jack housing, or farthest out in the female jack is critical for this method.
This makes wiring it up very easy since all you have to do is connect an alligator clip to that little pin. It's very close to the opening so it doesn't even have to go in very far.
But word of caution, if you put it too far in, then you won't get any video since it might short with ground or an audio pin. Shorting with ground should not damage the Raspberry Pi since a standard TRS (yes, only one R this time) will short the video and ground, so safety measures have been implemented to prevent damage.
In the second picture, you can notice the white alligator clip connected to the signal pin of an RCA connector and the black clip connected to the grounding part of the RCA connector. The other end of the RCA cable went into this little portable CRT tv you have - that can also accept composite video input.
Here the Video Pin(yellow) is connected to video clip of the 3.5mm jack of Pi-3 and the outer casing of video pin is connected to Ground Pin(Pin6) of the Pi3. Other end of RYB RCA connection goes to the Television End.